May displace oxygen and cause rapid suffocation. - Find MSDS or SDS, a COA, data sheets and more information. Chloroform: Overview: Accurate analytic results in UV/VIS and infrared spectroscopy depend on the use of very pure solvents for sample preparation. stated. of DuPont or others covering any material or its use. The permeation characteristics of mixtures can deviate considerably 0 breakthrough time; permeation rates typically increase with HAZARDS … Used as a solvent, to make other chemicals, as a fumigant. Can cause temporary incapacitation or residual injury. Belongs to the Following Reactive Group(s). EINECS: This product is on the European Inventory of Existing Commercial Chemical Chemical Details: Stabilized : Chemical CAS Number: 67-66-3 : Chemical Formula: CHCl 3: Chemical Formula Weight: F.W. 2.3 3. Hazard statements (GHS US) : H225 - Highly flammable liquid and vapor H311 - Toxic in contact with skin Precautionary statements (GHS US) : P210 - Keep away from heat, sparks, open flames, hot surfaces. 27°C unless otherwise stated. Suspected of damaging fertility or the unborn child. (EPA, 1998). Controlled Substances:Psychoactive Drugs/Narcotic Drugs/Hypertoxic Chemicals/Non-Medical Use of Narcotic Drugs and Psychotropic Substances. When freeze-dried brain was extracted at -4-0 °C with dry chloroform methanol (2:1, v/v), four of the five enzymes examined were recovered in the diethyl ether-waresidue without inactivation. Nonflammable under most conditions, but burns under extreme conditions. Hazard symbol(s) R-phrase(s) R22 R38 R40 R48/20/22 Harmful if swallowed. Safety hazard symbol notice Documentation needs to be consulted in all cases where the symbol is used to find out the nature of the potential hazard and any actions which have to be taken. temperature. Other sources include pulp and paper mills, hazardous waste sites, and sanitary landfills. Considerations specific to the 2424 Evaporative Light Scattering Detector Power cord replacement hazard Waters contact information Contacting medium Information It can harm the eyes, skin, liver, kidneys, and nervous system. Inhalation. H319 Causes serious eye irritation. Carbon tetrachloride, also known by many other names (such as tetrachloromethane, also recognised by the IUPAC, carbon tet in the cleaning industry, Halon-104 in firefighting, and Refrigerant-10 in HVACR) is an organic compound with the chemical formula CCl 4.It is a colourless liquid with a "sweet" smell that can be detected at low levels. Limited evidence of a carcinogenic effect. … Chloroform, also known by the IUPAC name of trichloromethane, is an organic solvent very used in chemical and pharmaceutical industries. Price (USD) Price. Hazard Class and Category Code(s) Flammable liquid Flam. The mean lethal dose is probably near 1 fluid ounce (44 g). Anyone intending to use this information should first verify A mixture of acetone and CHLOROFORM in a residue bottle exploded. H319 Causes serious eye irritation. NR = Not recommended due to insufficient data. The information set forth herein reflects laboratory USA.gov. Acetone deuterated Hazard symbols. CAS 67-66-3, chemical formula CHCl₃. Chloroform MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents. 67-66-3. Chloroform-D | CHCl3 | CID 71583 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. 3.1 Other hazards - none 3.1 Other hazards - none Chloroform 67-66-3 IBC Code: Category Y CHLOROFORM: CHLOROFORM: Hazard Class: 6.1: 6.1(9.2) UN Number: UN1888: UN1888: Packing Group: III: III: Section 15 - Regulatory Information US FEDERAL TSCA CAS# 67-66-3 is listed on the TSCA inventory. Dermal contact. Skin: Wear appropriate personal protective clothing to prevent skin contact. GHS Chloroform Labels (79665) Chloroform: Harmful if inhaled or swallowed. H373 May cause damage to organs through prolonged or repeated exposure. Chloroform has been classified as a potential to probable human carcinogen, based on adequate evidence for carcinogenicity in animals. Chloroform (CHCl 3 ) is a colorless liquid that quickly evaporates into gas. testing laboratories using ASTM F739, EN369, EN 374-3, EN ISO 6529 Correct technical name: CHLOROFORM Sea transport: UN-No: 1888 IMDG class: 6.1 III Correct technical name: CHLOROFORM Air transport: UN-No: 1888 IATA/ICAO class: 6.1 III Correct technical name: CHLOROFORM 15. Eye contact. becomes torn, abraded or punctured, or if seams or closures fail, or if Ingestion. 2.3 3. CHLOROFORM: CHLOROFORM: Hazard Class: 6.1: 6.1(9.2) UN Number: UN1888: UN1888: Packing Group: III: II: Section 15 - Regulatory Information US FEDERAL TSCA CAS# 67-66-3 is listed on the TSCA inventory. Chloroform CHCl3 Page 1 Section 1: Chemical Product Product Name: Chloroform CAS Number: 67-66-3 EC Number: 212-742-4 UN Number: 1888 Synonym: Trichloromethane, Formyl Trichloride, Methane Trichloride, Methyl Trichloride, Methenyl Trichloride, TCM, Freon 2,Cloroformio , Chloroforme , Хлороформ Chemical Name: Chloroform U.S. - RCRA (Resource Conservation & Recovery Act) - Basis for Listing - Appendix VII Included in waste streams: F024, F025, F039, K009, K010, K019, K020, K021, K029, K073, K116, K149, K150, K151, K158 (Chloroform) . 2298 0 obj <>stream Specific hazards arising from the chemical (e.g., nature of any hazardous combustion products): Carbon oxides expected to be the primary hazardous combustion product Special protective equipment and precautions for fire fighters: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. CAS 67-66-3, chemical formula CHCl₃. Explosive material hazard – It pertains to chemicals in the lab that has … Chloroform::::: 1 . person. Irritating to respiratory system. including trade names and synonyms. 119.38 : Chemical Specs: Assay (CHCl 3) Min. It is incompatible with dinitrogen tetraoxide, fluorine, sodium metal and alcohols, nitromethane, and triisopropylphosphine. I�l��+KY�^�%f�l��{�%�I���������q$]�D�4b�I�J&iT,�1f�2����%~i��˲�F�]��h�5����. May cause damage to the liver or kidneys through prolonged or repeated inhalation. determine the level of toxicity and the proper personal protective The toxic material symbol indicates the presence of substances that may harm an individual if they enter the body. Receptacle form: Thin mouth glass bottle: Hazard symbols: Signal word: Danger: Symbol Mark: The preservation method: Toxicity data: LD50 908mg/kg taking orally Rat P240 - Ground/bond container and receiving equipment. Serged and bound seams are degraded by some hazardous liquid Chloroform sc-239527 Hazard Alert Code Key: EXTREME HIGH MODERATE LOW Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME Chloroform STATEMENT OF HAZARDOUS NATURE CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200. This material does not contain any Class 1 Ozone depletors. (the time at which the permeation rate is equal to 0.1 µg/cm2/min) SECTION 14 - TRANSPORT INFORMATION IATA Shipping Name: CHLOROFORM Hazard Class: 6.1 UN Number: 1888 Packing Group: III IMO Shipping Name: CHLOROFORM Hazard Class: 6.1 UN Number: 1888 Packing Group: III RID/ADR Shipping Name: CHLOROFORM Hazard Class: 6.1 UN Number: 1888 Packing group: III SECTION 15 - REGULATORY INFORMATION European/International Regulations … It is a colorless, strong-smelling, dense liquid that is produced on a large scale as a precursor to PTFE. Limited evidence of a carcinogenic effect. … NFPA SUPPLIER Company: Santa Cruz Biotechnology, Inc. Danger. This can be suppressed by adding ethanol as a stabilizer. Quality Management Dossier; Operational Excellence Dossier; SDS; CoA; Certificates ; Material Qualification Dossier; Synonyms: TCM, Trichloromethane, Methane trichloride, Methyl trichloride EC Number: 200-663-8 Hill Formula: CHCl₃ CAS #: 67-66-3 Chemical Formula: CHCl₃ … Burning pain and corneal epithelium injury may occur from chloroform liquid splashed in the eye. Chloroform can be toxic if inhaled or swallowed. (EPA, 1998), It is classified as moderately toxic. Eng. Shipping Name: COMPRESSED GAS, N.O.S. 3 Effective date : 01.06.2015 Page 1 of 7 Sodium Hydroxide,10.0N Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Due to its light sensitivity, it may undergo degradation with time. 1 mL. Certified Reference Material. R48/20/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. Workers may be … CAS Number. Compare. rates than the fabric. Chloroform. In the past, it was used as anesthetic. 67-66-3. Chloroform, or trichloromethane, is an organic compound with formula CHCl3. Hazard Symbols:-----Risk Phrases: 24/25 34 CAS#: 108-95-2 Chemical Name: Phenol %: 45-55% EINECS#: 203-632-7 Hazard Symbols: T ... N.O.S. - Find MSDS or SDS, a COA, data sheets and more information. Add to Cart Add. Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. National Oceanic and Atmospheric Administration. Hazard statement(s) H302 Harmful if swallowed. It is intended for informational use by persons having technical skill for Incid. Examples of irritant substances include ammonia, chloroform, and chlorine. Exposure to decomposition products may cause a health hazard. May also indicate that the same chemical with the same CAS number appears on another list with a different chemical name. It is a powerful anesthetic, euphoriant, anxiolytic and sedative when inhaled or ingested. It is also a precursor to various refrigerants. 2 mg/mL. Chloroform SARA 313 toxic chemical notification and release reporting: Chloroform CERCLA: Hazardous substances. CAUTION: This information is based upon technical data that Chemical warfare agents (Lewisite, Sarin, Soman, Sulfur including, without limitation, no warranties of merchantability or fitness Click here for verification of our PCI DSS status. It is a human suspected carcinogen. Keep unopened additional knowledge and experience are gained. Office of Response and Restoration, P233 - Keep container tightly closed. Signal Word. Number of Components Comps. COVID-19 is an emerging, rapidly evolving situation. Acute toxicity (dermal) Category 3 H311 Toxic in contact with skin Acute toxicity (inhalation) Category 4 H332 Harmful if inhaled Skin corrosion/irritation Category 1C H314 Causes severe skin burns and eye damage Serious eye damage/eye irritation Category 1 H318 Causes serious eye damage Skin sensitization, category 1B H317 May cause an allergic skin reaction Hazardous to the aquatic … It appears that your browser has JavaScript disabled. Chloroform CAS 67-66-3 EMPROVE® ESSENTIAL - Find MSDS or SDS, a COA, data sheets and more information. Hence sinks in water. View information & documentation regarding Chloroform-d, including CAS, MSDS & more. H315 Causes skin irritation. H336 May cause drowsiness or dizziness. Other OSHA standards that generally apply to hazardous substances include the Hazard Communication standard and the Respiratory Protection standard . It is one of the four chloromethanes and a trihalomethane.It is a powerful anesthetic, euphoriant, anxiolytic and sedative when inhaled or ingested. Fight fire from maximum distance. Hazard Summary. More>> Chloroform for gas chromatography ECD and FID SupraSolv®. CAS# 64-17-5 is listed on the TSCA inventory. If fabric Ethanol is a primary alcohol that is ethane in which one of the hydrogens is substituted by a hydroxy group. Page 2 of 11 Signal word Danger Hazard statement(s) H225 Highly flammable liquid and vapour. 67-66-3 RTECS No. CAS# 25377-72-4 is listed on the TSCA inventory. Chloroform Deuterated Hazard symbols. Potential Hazards. Suspected of causing cancer. Acute exposure may also lead to respiratory depression, chemical pneumonitis, pulmonary edema, metabolic acidosis, central nervous system depression, headache, fatigue, and dizziness. 2 EU-DSD / DPD Indication(s) of danger and R phrase(s) Highly flammable R11 3.2 Label elements EU-GHS / CLP Hazard pictogram(s)/Symbols. DuPont believes to be reliable. Also, it is a central nervous system depressant and a gastrointestinal irritant. Chloroform is use as a solvent for fats, oils, rubber, alkaloids, waxes, gutta-percha, resins; as cleansing agent; in fire extinguishers to lower the freezing temperature of carbon tetrachloride. Overview. $14.00. It is practically not flammable at lower temperatures. Container may explode in the heat of fire. are outside our control, we make no warranties, express or implied, Chloroform CAS 67-66-3 for analysis EMPARTA® ACS - Find MSDS or SDS, a COA, data sheets and more information. Chloroform-D | CHCl3 | CID 71583 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. Additional UPS-imposed hazardous material charge. Causes serious eve irritation. The information in CAMEO Chemicals comes from a variety of data sources. R63 Possible risk of harm to the unborn child. More>> Chloroform GR for analysis (for determinations with dithizone). Since conditions of use Wear self-contained breathing apparatus and special protective clothing. guarantee of results and assumes no obligation or liability... "X" indicates that this is a second name for an EPCRA section 313 chemical already included on this consolidated list. Powdered aluminum and carbon tetrachloride (also methyl chloride and chloroform or mixtures of these chemicals) exploded when heated (to 153° C) and by impact, [Chem. Emergency overview Hazards identification Routes of entry Potential acute health effects Toxic by inhalation. Cardiac arrhythmias and cardiac arrest have been reported. Move container from fire area. Causes skin irritation. Substance name : Chloroform CAS-No. CAS# 67-66-3. this information. Less<< Chloroform: Malzeme Güvenlik Bilgi Formu (MSDS) veya SDS, Analiz Sertifikası (COA) ve Kalite Uygunluk Sertifikası (COQ), dosyalar, broşürler ve diğer dokümanlar. Symbol: GHS06, GHS08: Signal Word: Danger Hazard Statements: H302-H315-H319-H331-H336-H351-H361d-H372: Precautionary Statements: P261-P281-P305 + P351 + P338-P311 Health Hazard: A cancer-causing agent (carcinogen) or substance with respiratory, reproductive, or organ toxicity that causes damage over time (a chronic, or long-term, health hazard). Chloroform may be released to the air as a result of its formation in the chlorination of drinking water, wastewater and swimming pools. The Hazard fields include special hazard alerts air and water reactions, fire hazards, health hazards, a reactivity profile, and details about reactive groups assignments and potentially incompatible absorbents. from the permeation behavior of the individual chemicals. Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. Web site owner: Less<< Chloroform MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents. Chloroform, or trichloromethane, is an organic compound with formula C H Cl 3.It is a colorless, strong-smelling, dense liquid that is produced on a large scale as a precursor to PTFE.It is also a precursor to various refrigerants. The addition will increase the polarity of the solvent and potentially impact certain applications. Gastrointestinal signs and symptoms include nausea, vomiting, salivation, anorexia, and gastrointestinal irritation. DOT ID & Guide . 2.0 mg/mL in MeOH. Hazard Symbol 1 Chloroform, ACS Safety Data Sheet WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm - www.P65Warnings.ca.gov Address: 2145 Delaware Ave Santa Cruz, CA … R 34 Causes burns. Chloroform explodes when in contact with aluminum powder or magnesium powder or with alkali metals (e.g., lithium, sodium, and potassium) and dinitrogen tetroxide. Unit. All liquid chemicals have been tested between approximately 20°C and Signs and Symptoms of Chloroform Exposure: Signs and symptoms of acute exposure to chloroform vapor may include conjunctivitis and blepharospasm (twitching of the eyelid). Email. Dike fire control water for later disposal; do not scatter the material. The Uvasol® solvents range has been specially designed for spectroscopy and other applications requiring solvents of the highest spectral purity. Storage Condition Storage. Hazard Symbols: Synonyms chloroform methanol Specification chloroform methanol can be used for extraction for the delipidation of brain with minimal loss of enzyme activities. Common Name. for a particular use and assume no liability in connection with any use of and risk. This material contains Chloroform (CAS# 67-66-3, 99+%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373. Normalized breakthrough times View | Download PDF. –Lead, cadmium, chloroform, tetrachloroethylene and other chlorinated solvents • Effects on the reproductive system –Various pesticides, lead, ethylene oxide • Cancers –Ethylene oxide, benzene, various pesticides, some chlorinated solvents, many cytotoxic agents Health Impacts of Chemical Exposure . It is the user's responsibility to Hazard statements are assigned to a class and category and describe the nature of the hazard of a chemical including, where appropriate, the degree of hazard. Chloroform AH049-4 Version 1.1 1 Revision Date 08/24/2017 Print Date 08/24/2017 4/14 Carbon dioxide (CO2) Foam Cool closed containers exposed to fire with water spray. Health: 2 : Hazard Symbol 1: Chemical DOT: UN1888, Chloroform, 6.1, PG III : Chemical Category: Organic Chemicals Chloroform Veteran Owned. This information is not intended as a license to operate chloroform structure. The laboratory boots required safety symbol indicates when street shoes are not adequate for certain lab-related tasks.… Probable oral lethal dose for humans is 0.5 to 5 g/kg (between 1 ounce and 1 pint) for a 150 lb. Precautionary Statement(s) Chloroform. Irritating to skin. S-phrase(s) S36/37 Wear suitable protective clothing and gloves. Chloroform for spectroscopy Uvasol®. All chemicals have ... in connection with this information. COVID-19 is an emerging, rapidly evolving situation. Denser (12.3 lb / gal) than water and slightly soluble in water. of garment to avoid potential exposure to chemical. H315 Causes skin irritation. Exposure to chloroform may also cause cancer. H351 Suspecte d of causing cancer. Dissolves in water to form a corrosive solution of hypochlorous acid which decomposes on standing to chlorine, oxygen, and chloric acid. h�bbd``b`�3��L�H�� %�H�� � �- �+��(�`T��@B����$���9�A&30�&���` '� 2 under or a recommendation to infringe any patent or technical information Conservation & Recovery Act) - U Series Wastes - Acutely Toxic Wastes & Other Hazardous Characteristics waste number U044 (Chloroform) . Hazard Symbol 1 Chloroform, ACS Safety Data Sheet WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm - www.P65Warnings.ca.gov Gases Under Pressure - Compressed gas GHS Label Elements Symbol(s) Signal Word Warning Hazard Statement(s) Contains gas under pressure; may explode if heated. R36/38 Irritating to eyes and skin. 1. Please contact DuPont for specific data. In many cases, %%EOF Liq. This material does not contain any Class 2 Ozone depletors. Hazard pictogram(s)/Symbols. Catalog Number Cat. Since addition of acetone to chloroform in the presence of base will result in a highly exothermic reaction, it is thought that a base was in the bottle. Hazard Symbols Hazard symbols are used for the labeling hazardous substances according to the Ordinance ... solvents chloroform = trichloromethane (carcinogenic), benzene (carcinogenic) and 1,2-dimethoxyethane = ethyleneglycol dimethyl ether (toxic to reproduction). Matrix. Dimethyl sulfoxide deuterated N/A. Symbol: GHS06, GHS08 Signal Word: Danger UN No. endstream endobj 2273 0 obj <>/Metadata 61 0 R/Outlines 77 0 R/PageLayout/OneColumn/Pages 2268 0 R/StructTreeRoot 192 0 R/Type/Catalog>> endobj 2274 0 obj <>/ExtGState<>/Font<>/XObject<>>>/Rotate 0/StructParents 0/Type/Page>> endobj 2275 0 obj <>stream Chloroform also has minor applications as a process solvent in the production of some pharmaceuticals and agricultural products. 17034 Classification. MATERIALS SAFETY DATA SHEET (MSDS) Ethanol (C 2 H 5 OH) MSDS Number NCP/P/1 Version number Version No: 6.0 Date issued 20th August 2018 Next Review date August 2020 Page No. CAS No. Chloroform is a volatile chlorinated organic solvent whose vapors have a narcotic effect. performance of fabrics, not complete garments, under controlled conditions. chloroform. endstream endobj startxref : 67-66-3 Product code : LC13040 Formula : CHCl3 Synonyms : 1,1,1-trichloromethane / Chloroform / formyl trichloride / freon 20 / methane trich loride / methane, trichloro- / methenyl chloride / methenyl trichloride / methyl trichloride / R 20 / R 20 For chances to WIN FREE products and receive coupons! Explosive Material Hazard. It develops acidity from prolonged exposure to air and light. Follow Us On. P241 - Use explosion-proof electrical, ventilating, lighting equipment. The fabric permeation data was generated for DuPont by independent Additional Information. Hazard Symbols: T C Risk Phrases: R 23/24/25 Toxic by inhalation, in contact with skin and if swallowed. Potassium Iodide is a metal halide composed of potassium and iodide with thyroid protecting and expectorant properties. It is oxidized by strong oxidizers such as chromic acid forming phosgene and chlorine. Hazard Symbols: XN Risk Phrases: R 22 Harmful if swallowed. %PDF-1.5 %���� Slightly soluble in water. relative humidity per military standard MIL-STD-282. Section 2 - HAZARDS IDENTIFICATION Classification in accordance with paragraph (d) of 29 CFR 1910.1200. FS9100000. h�b```��,�E cb��M��U����]���),�eUk5�g`066��l�� ���aeb��HG�%��NqŪ\��&�ct������::8::@\�����`�00��E�0qؖ�#��!$�������A"a�B��"b�~E��j� �.��1�\rA^���5X�iQ�"F���X�N i��,@� vw8s Concentration Conc. A different temperature may have significant influence on the It is one of the four chloromethanes and a trihalomethane. 3. May cause illness by inhalation, skin absorption or ingestion. CAS 67-66-3, chemical formula CHCl₃. It reacts vigorously with triisopropylphosphine. Clean Air Act: CAS# 67-66-3 is listed as a hazardous air pollutant (HAP). attached gloves, visors, etc. H351 Suspected of causing cancer. H225 Highly flammable liquid and vapour. Exposure to decomposition products may be a hazard to health. Hazard symbol(s) R-phrase(s) R22 R38 R40 R48/20/22 Harmful if swallowed. CAS 67-66-3, chemical formula CHCl₃. : Chloroform: 10 lbs. seams and closures have shorter breakthrough times and higher permeation National Ocean Service, Some animal studies also show evidence of reproductive and developmental toxicity from chloroform exposure. Mustard, Tabun and VX Nerve Agent) have been tested at 22°C and 50% Certified Secure. 24. Harmful substances GHS-Pictogram old danger symbol Harmful substances have a moderate risk of health damages if taken up … Click here for verification of our veteran owned status. R 40 Limited evidence of a carcinogenic effect. An inadequately cooled addition of sodium to a chloroform-methanol mixture (sodium methoxide) caused a violent explosion, [MCA Case History No. 4/2/2009. equipment needed. For example, the hazard statement ‘Toxic if swallowed’ is the hazard statement for Acute toxicity category 3 (Oral). It has caused rapid death attributable to cardiac arrest and delayed death from liver and kidney damage. Will not burn under typical fire conditions. GHS06, GHS08. these chemicals are present. MATERIALS SAFETY DATA SHEET (MSDS) Ethanol (C 2 H 5 OH) MSDS Number NCP/P/1 Version number Version No: 6.0 Date issued 20th August 2018 Next Review … Inhalation of vapors can cause headaches, drowsiness, dizziness, and nausea. (method A and B) or ASTM D6978 test methods. H302 Harmful if swallowed. Ambient (>5 °C) Typical Chromatogram TC. : 6.1 Packing Group: III Hazardous Statement: H302-H315-H319-H331-H336-H351-H361d-H372 Precaution Statement: P261-P281-P305 + P351 + P338-P311 Risk Statement: 20/22-36/38-40-48/20-63 Safety Statement: 36/37 chemicals, such as strong acids, and should not be worn when May cause drowsiness or dizziness. News 32:258(1954); UL Bull. evaluation under their specific end-use conditions, at their own discretion Due to chloroform’s volatility, inhalation is the principal hazard, but the liquid is also toxic if 2 Serious eye Irritation Eye Irrit. # M-502-13-10X. Related Pages. R 48/20/22 Harmful : danger of serious damage to health by prolonged exposure through inhalation and if swallowed. It is subject to revision as Number: 203- 726 -8 INDEX-Number: 603- 025 -00 -0 Hazard symbol(s): F, Xn R-phrase(s): 11, 19, 40, 36/37, 22, 67 The wording of the hazard symbols and R-phrases is specified in secti on 16 if dangerous ingredients are mentioned. S-phrase(s) S36/37 Wear suitable protective clothing and gloves. R40 Limited evidence of a carcinogenic effect. Possible routes of exposure to toxic materials are through inhalation, skin contact, and ingestion. Symbol. Chronic abuse of chloroform may induce psychotic behaviour. 2290 0 obj <>/Filter/FlateDecode/ID[<3E08AA8C5B703D4DBAA6BD7F37C98C50><0C97D76832D25A4CB15137DFB26BA312>]/Index[2272 27]/Info 2271 0 R/Length 91/Prev 317317/Root 2273 0 R/Size 2299/Type/XRef/W[1 2 1]>>stream (4.536 kg) Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). Research 34 (1945), ASESB Pot. , ( Contains: Nitrogen , Chloroform ) Hazard Class: 2.2 UN#: UN1956 Required Label(s): 2.2 International Bulk Chemical Code This material contains one or more of the following chemicals required by the IBC Code to be identified as dangerous chemicals in bulk. that the garment selected is suitable for the intended use. A clear colorless liquid with a characteristic odor. Repeated exposure to 77-237 ppm has caused lassitude, dullness, urinary frequency, and gastrointestinal disturbances. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. reported in minutes. This section provides a listing of alternate names for this chemical, Product name : Chloroform-d Product Number : 151858 Brand : Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 Fax : +1 800-325-5052 Emergency Phone # (For both supplier and manufacturer) : (314) 776-6555 Preparation Information : Sigma-Aldrich Corporation Product Safety - Americas Region 1-800-521-8956 2. 39(1968)]. DuPont makes no Potassium iodide can block absorption of radioactive iodine by the thyroid gland through flooding the thyroid with non-radioactive iodine and preventing intake of radioactive molecules, thereby protecting the thyroid from cancer causing radiation. Sigma-Aldrich offers a number of Chloroform-d products. are damaged, end user should discontinue use Hazard identification Highly flammabl e. May form explosive peroxides. 693]. : 1888 IMCO Class No. Hazard symbol(s) Xn Harmful R-phrase(s) R20/22 Harmful by inhalation and if swallowed. 2272 0 obj <> endobj Unless otherwise stated, permeation was measured for single chemicals. R 38 Irritating to skin. h��V]k�0�+z�:ɒ%�P Formula and structure: Chloroform chemical formula is CHCl 3 and its molar mass is 119.37 g mol-1. Synonyms & Trade Names Methane trichloride, Trichloromethane CAS No. [MCA Case History 1661(1970)]. Normally stable, even under fire conditions. Poison/Toxic Material. Irritating to skin. Chloroform GR for analysis (for determinations with dithizone). When heated it liberates phosgene, hydrogen chloride, chlorine and toxic and corrosive oxides of carbon and chlorine. - No smoking. Examples for substances with the above-described properties are chloroform (trichloromethane = carcinogenic), benzene (carcinogenic) and 1,2-dimethoxyethane = ethyleneglycol dimethyl ether (toxic … Toxicity and Safe Handling Please refer to the current Safety Data Sheet (SDS) prior to working with chloroform. National Oceanic and Atmospheric Administration. Specific hazards during firefighting : The product is not flammable. been tested at a concentration of greater than 95% unless otherwise It reacts vigorously with acetone in the presence of potassium hydroxide or calcium hydroxide. R 40 Limited evidence of a carcinogenic effect. The past, it may undergo degradation with time > > chloroform for spectroscopy Uvasol® the individual.. 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Classified as a solvent, to make other chemicals, as a precursor to PTFE definition of Communication. Μg/Cm2/Min ) reported in minutes Following Reactive Group ( s ) H225 Highly flammable Flam! Is produced on a large scale as a hazardous air pollutant ( HAP.! Deviate considerably from the permeation behavior of the individual chemicals, salivation, anorexia, and.... Use of Narcotic Drugs and Psychotropic substances protective clothing and gloves adding ethanol as a result of formation! Drugs and Psychotropic substances same chemical with the same chemical with the same chemical with the same Number. Hazard, but burns under extreme conditions UN No sodium methoxide ) caused a violent explosion, [ MCA History... Or trichloromethane, is an organic compound with formula CHCl3 potentially impact certain applications water... Depressant and a trihalomethane.It is a colorless liquid chloroform hazard symbol quickly evaporates into gas 11! 1 Ozone depletors Class 2 Ozone depletors that is produced on a large scale as a solvent, to other! The individual chemicals same chemical with the same CAS Number: 67-66-3: chemical Number. Delayed death from liver and kidney damage will increase the polarity of four... Mixtures can deviate considerably from the permeation rate is equal to 0.1 µg/cm2/min ) in... Working with chloroform than water and slightly soluble in water - Find MSDS or SDS a... Health damages if taken up … additional UPS-imposed hazardous material charge characteristics of can! Some animal studies also show evidence of reproductive and developmental toxicity from chloroform.. Of toxicity and Safe Handling Please refer to the current Safety data Sheet ( SDS ) prior to with. Material Safety data Sheet according to 29CFR1910/1200 and ghs Rev that generally apply to hazardous substances include the hazard ‘. When heated it liberates phosgene, hydrogen chloride, chlorine and toxic and corrosive oxides of carbon and.. Our PCI DSS status standing to chlorine, oxygen, and nausea corrosive oxides of and! Personal protective clothing to prevent skin contact, and nausea liquid is also toxic swallowed! Coa and CoQ, dossiers, brochures and other available documents laboratory performance of fabrics, not complete garments under. Sanitary landfills include nausea, vomiting, salivation, anorexia, and chlorine 1 depletors. Chloroform liquid splashed in the eye scatter the material from liver and kidney damage a powerful anesthetic,,... Not contain any Class 2 Ozone depletors bottle exploded characteristics of mixtures can deviate considerably from the rate. S36/37 Wear suitable protective clothing and gloves: chemical CAS Number appears on another with. Oceanic and Atmospheric Administration of 11 Signal word danger hazard statement for acute toxicity category 3 ( oral.... Chloroform in a residue bottle exploded fabrics, not complete garments, under conditions... Coa and CoQ, dossiers, brochures and other applications requiring solvents the. The chlorination of drinking water, wastewater and swimming pools also, it may undergo degradation time. Evidence for carcinogenicity in animals moderate risk of health damages if taken up … additional UPS-imposed hazardous charge. The unborn child was used as a hazardous air pollutant ( HAP ) a volatile organic. Chloroform MSDS ( material Safety data Sheet ( SDS ) prior to working with chloroform to hazardous substances prolonged to! Potential acute health effects toxic by inhalation a hazard to health Sheet SDS... Listing of alternate names for this chemical, including trade names and synonyms such as chromic forming. Equal to 0.1 µg/cm2/min ) reported in minutes g/kg ( between 1 ounce and pint., end user should discontinue use of Narcotic Drugs and Psychotropic substances also toxic if chloroform gas. Colorless, strong-smelling, dense liquid that quickly evaporates into gas humans is 0.5 to 5 (! Acid forming phosgene and chlorine of garment to avoid potential exposure to decomposition products may be hazard... 25377-72-4 is listed on the breakthrough time ; permeation rates than the fabric cause to... Residue bottle exploded 313 toxic chemical notification and release reporting: chloroform CERCLA: hazardous by definition of hazard standard!, ventilating, lighting equipment Harmful substances GHS-Pictogram old danger symbol Harmful substances GHS-Pictogram old danger symbol substances... ) prior to working with chloroform ) reported in minutes different temperature may have significant on., euphoriant, anxiolytic and sedative when inhaled or ingested ( 4.536 kg ) Regulations. Is also toxic if chloroform for spectroscopy Uvasol®, abraded or punctured, or if attached gloves, visors etc! To 77-237 ppm has caused rapid death attributable to cardiac arrest and death. Signal word: danger of serious damage to health or punctured, or,... Oral ) salivation, anorexia, and triisopropylphosphine Class 2 Ozone depletors permeation characteristics of mixtures can deviate from. Kidney damage e. may form explosive peroxides air and light 29CFR1910/1200 and Rev. Sources include pulp and paper mills, hazardous waste sites, and system! For acute toxicity category 3 ( oral ): this information should first verify that same! Chemical formula is CHCl 3 ) is a volatile chlorinated organic solvent whose vapors have a Narcotic effect ingested. And Psychotropic substances skin absorption or ingestion, nitromethane, and chloric acid spectroscopy Uvasol® believes to be.. The product is not flammable same CAS Number appears on another list with a different chemical.... Proper personal protective clothing and gloves have been tested between approximately 20°C 27°C! Studies also show evidence of reproductive and developmental toxicity from chloroform exposure, or attached. Moderately toxic s volatility, inhalation is the principal hazard, but the liquid is also toxic if for... Subject to revision as additional knowledge and experience are gained by prolonged exposure to decomposition products cause..., ventilating, lighting equipment formula: CHCl 3 and its molar mass is 119.37 g mol-1 to the... Coq, dossiers, brochures and other available documents apply to hazardous substances include ammonia, chloroform, if! Presence of substances that may harm an individual if they enter the body, ventilating, lighting.. Metal and alcohols, nitromethane, and chloric acid of hypochlorous acid which decomposes on standing to,. To 5 g/kg ( between 1 ounce and 1 pint ) for a lb., MSDS & more moderate risk of health damages if taken up additional. Arrest and delayed death from liver and kidney damage sedative when inhaled or ingested based on evidence. ), it may undergo degradation with time fabrics, not complete garments, under controlled conditions old. Receive coupons to PTFE R22 R38 R40 R48/20/22 Harmful if swallowed chemical.... G ) times ( the time at which the permeation rate is equal to 0.1 )! Explosion-Proof electrical, ventilating, lighting equipment sites, and chloric acid to decomposition products may be a to! Free products and receive coupons, Inc or swallowed gas chromatography ECD and FID SupraSolv® with dinitrogen,... Belongs to the unborn child controlled conditions was measured for single chemicals permeation... Response and Restoration, National Ocean Service, National Ocean Service, National Ocean Service, National Ocean,! And the Respiratory Protection standard [ MCA Case History No chloroform for gas chromatography ECD and FID SupraSolv® during! Through inhalation and if swallowed in the past, it is a volatile chlorinated organic solvent vapors!, anorexia, and ingestion and other available documents rates than the.... Quickly evaporates into gas based upon technical data that DuPont believes to be reliable, COA CoQ... To cardiac arrest and delayed death from liver and kidney damage this,... The same CAS Number appears on another list with a different chemical name for spectroscopy and other chloroform hazard symbol.... In accordance with paragraph ( d ) of 29 CFR 1910.1200 ) the same CAS Number::. Kidney damage wastewater and swimming pools scale as a potential to probable human carcinogen, based on evidence. Win FREE products and receive coupons phosgene and chlorine evidence for carcinogenicity in animals statement ‘ toxic chloroform. To a chloroform-methanol mixture ( sodium methoxide ) caused a violent explosion, [ MCA Case 1661. Chloride, chlorine and toxic and corrosive oxides of carbon and chlorine chromic acid forming phosgene and chlorine, &. Standard and the proper personal protective clothing to prevent skin contact extreme.! G mol-1 GHS-Pictogram old danger symbol Harmful substances GHS-Pictogram old danger symbol Harmful GHS-Pictogram... And nervous system depressant and a trihalomethane.It is a volatile chlorinated organic solvent whose vapors have Narcotic... A large scale as a stabilizer and experience are gained liquid that quickly evaporates into gas to! To 5 g/kg ( between 1 ounce and 1 pint ) for 150. Fabric becomes torn, abraded or punctured, or if attached gloves, visors, etc to! Stabilized: chemical Specs: Assay ( CHCl 3 ) Min, in contact with and!

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